President Petro Poroshenko called the survey as he intends to concrete another course for the nation after the removing of professional Russian pioneers recently.
He additionally made a shock visit to the fretful Donbass area, the site of a proceeding with expert Russian uprising.
Around 3m individuals in the eastern Donetsk and Luhansk districts in Donbass won’t partake in the vote.
The separatists in eastern Ukraine plan to hold their own particular surveys one month from now.
An alternate 1.8 million individuals in Crimea, attached by Russia in March, will likewise not tune in.
Ukraine vote map
The vote additionally comes in the midst of a vitality emergency, with Russia slicing off gas supplies to Ukraine in June in a disagreement regarding unpaid bills.
Ukraine’s economy is caving in, with GDP estimate to fall somewhere around 7 and 10% not long from now.
On Sunday, Mr Poroshenko’s official Twitter account said that he had landed in the Donbass locale, without indicating where.
Global eyewitnesses have communicated “genuine concerns” over the impact the viciousness in the east of the nation is having on the race.
Photograph of Petro Poroshenko, obviously in Donbass, 26 October Ukraine’s leader said he had gone by the anxious Donbass district on surveying day
The leader of an Organization for Security and Cooperation in Europe (OSCE) onlooker mission, Swedish MP Kent Harstedt, said this was the most difficult of every last one of decisions he had watched.
He dreaded it would hard to contact a huge number of removed individuals in eastern Ukraine, additionally said he trusted the survey could be a defining moment.
OSCE screens are likewise display in Moscow to watch voting by the assessed two to three million Ukrainian natives there.
A large portion of the 450 seats in parliament will be dispensed relatively as per a gathering rundown framework, with gatherings expecting to increase more than 5% to win seats.
An alternate 198 Mps will be chosen from individual voting public, with 27 from Crimea and the dissident held zones staying empty.
The primary gatherings vying for seats are:
Mr’s Poroshenko Bloc, containing his Solidarity gathering and Udar, headed by boxer Vitali Klitschko
Executive Arseny Yatsenyuk’s People’s Front
Oleh Lyashko’s patriot Radical Party
Previous Prime Minister Yulia Tymoshenko’s Fatherland Party
Most are patriot and master Western, and expelled President Viktor Yanukovych’s Party of Regions is not running.
In any case, three gatherings involving his previous associates are looking for votes in the south and east of the nation.
Mr Yanukovych fled in February after a wave of genius Western dissents in Kiev activated by his refusal to consent to an organization arrangement with the European Union.
Ukrainian warriors stack an explosive launcher at their position in the town of Bugas in the Donetsk locale, on 24 October 2014 Government strengths are even now battling separatists in the Donetsk district in eastern Ukraine
Outrage in eastern Ukraine at his oust turned to agitation with separatists seizing government structures and starting a revolt in April.
No less than 3,700 individuals have been slaughtered since the clash started, including 300 executed after a truce was concurred on 5 September.
On Friday Russian President Vladimir Putin said surprisingly that Moscow had helped Mr Yanukovych escape.